Tesis y Trabajos de Investigación PUCP
URI permanente para esta comunidadhttp://54.81.141.168/handle/123456789/6
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Ítem Texto completo enlazado Biopolymer composites as triboelectric layers for the development of triboelectric nanogenerator (TENG)(Pontificia Universidad Católica del Perú, 2024-08-29) Delgado De Lucio, Virgilio Brian; Torres García, Fernando GilbertoThe escalating global energy demand, propelled by rapid industrial expansion, has underscored the imperative of transitioning to cleaner and more sustainable energy sources to combat pollution and mitigate the adverse effects of global warming. Triboelectric nanogenerators (TENGs) have emerged as a promising technology capable of harnessing ambient mechanical energy and converting it into electrical power. This research initiative seeks to advance the field by focusing on the development of composite materials derived from a synergy of biopolymers extracted from natural sources, particularly potatoes, and inorganic fillers. The comprehensive objectives of this study encompass the extraction of biopolymers from natural resources, the meticulous characterization of composite materials to ascertain their mechanical, physicochemical, and morphological properties, the fabrication of TENGs employing these composite materials, and an exhaustive evaluation of the TENGs' performance metrics. Remarkably, the composite materials exhibit outstanding dielectric properties, characterized by exceptional dielectric permittivity (ε) values. At a fundamental level, these materials showcase impressive dielectric constant (ε') values, with specific examples reaching into the millions at a frequency of 1 Hz. Furthermore, the dielectric loss (ε'') values, representing the imaginary component of permittivity, also exhibit notable characteristics. For instance, certain composite materials demonstrate ε'' values that mirror the remarkable ε' values, signifying their potential to excel in energy storage applications. What sets this research apart is not only the development of materials with exceptional dielectric properties but also the exploration of their practical application in triboelectric nanogenerators. The TENGs fashioned from these composite materials consistently exhibit remarkable voltage outputs, further underscoring their potential for various energy harvesting applications.Ítem Texto completo enlazado Synthesis, tribology, electro-tribology and mechanical performance of ti2alc and ti3alc2 max phases thin films(Pontificia Universidad Católica del Perú, 2023-01-26) Quispe Dominguez, Roger; Grieseler, RolfThis thesis investigates the synthesis, mechanical properties, tribological and electro-tribological behavior of Ti2AlC and Ti3AlC2 MAX phases in the form of thin films. The thin films were obtained by deposition of a multilayer system of Titanium (Ti) - Aluminum (Al) - Carbon (C) and subsequent thermal annealing in a vacuum and controlled atmosphere. The Ti-Al-C multilayer system was deposited by magnetron sputtering on silicon substrates with a SiO2 and SixNy double-layer diffusion barrier. The stoichiometric of the film was controlled through the thickness of the individual monolayers. To obtain a 500 nm thick film, the Ti-Al-C sequence was repeated 22 times with individual thicknesses of 14, 6 and 3.5 nm, respectively. The experimental results show that the Ti2AlC phase is formed at a temperature of 700°C, while the Ti3AlC2 phase is formed at 950°C. The structural properties of the thin films were characterized by X-ray diffraction, Raman microscopy and glow discharge optical emission spectroscopy (GD-OES). The hardness of the thin films was analyzed by nanoindentation tests, obtaining hardness values of 11.6 and 5.3 GPa for Ti2AlC and Ti3AlC2, respectively. The tribological behavior of the thin films was analyzed under dry sliding conditions using a ball-on-flat reciprocating tribometer. The counter body consisted of AISI 52100 steel balls of 3 mm diameter. The friction coefficients obtained were in the range of 0.21 - 0.2 and 0.6 - 0.91 for the Ti2AlC and Ti3AlC2 thin films, respectively. The Ti2AlC phase has a better tribological performance, which can be attributed to its smaller grain size, lower surface roughness and higher hardness compared to the Ti3AlC2 phase. The electrical resistivity of the thin films was 0.73 and 0.45 μΩ·m for Ti2AlC and Ti3AlC2, respectively. The electro-tribological test was carried out using a ball-on-flat reciprocating tribometer under electrical currents of 10, 50 and 100 mA. The coefficient of friction and the electrical contact resistance were measured simultaneously in the same test. The results show that the coefficient of friction and electrical contact resistance could be related to thin-film properties such as hardness, roughness, grain size, and resistivity. These results of the electro-tribological behavior of the films provide valuable information for possible applications such as sliding electrical contacts.Ítem Texto completo enlazado Implementation of a triboelectrical workstation for the investigation of the influence of electrical current on the tribological properties of thin films(Pontificia Universidad Católica del Perú, 2016-06-20) Yupanqui Aliaga, Edson Igor; Ströhla, Tom; Rumiche Zapata, Francisco AurelioCon el fin de hacer que las máquinas, circuitos electrónicos o contactos eléctricos para diversas aplicaciones, funcionen correctamente; es necesario conocer sus características. La mayoría de las máquinas desarrolladas o dispositivos electrónicos están formados por varios componentes que están interconectados. Cuando estos componentes interactúan entre sí o con el medio ambiente, están sometidos a estrés, fricción y desgaste. Por lo tanto, se requiere predecir el comportamiento de estos materiales cuando están sometidos a fricción y desgaste para así tener una interpretación adecuada de lo que ocurre en estos puntos de contacto. La presente tesis se centra en la caracterización de materiales por medio de un sistema tribológico basado en un "punto plano-contacto", donde una bola estacionaria hace de punto y el material de muestra se hace oscilar debajo. Con este sistema es posible determinar el valor de la fuerza tangencial y la fuerza normal, y a partir de estos dos, se puede calcular el coeficiente de fricción. Además, apoyamos el análisis de materiales mediante una caracterización eléctrica en paralelo durante el experimento. Para este propósito, una corriente se inyecta en la muestra. Luego, la caída de tensión y la corriente son medidas y con estos datos, la resistencia eléctrica se puede determinar. El sistema de medición está controlado por un ordenador central que usa LabVIEW y los datos medidos son almacenados para su posterior análisis.